Petroleum
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Petroleum, or crude oil, naturally occurring oily, bituminous liquid composed of various organic chemicals. It is found in large quantities below the surface of Earth and is used as a fuel and as a raw material in the chemical industry. Modern industrial societies use it primarily to achieve a degree of mobility—on land, at sea, and in the air—that was barely imaginable less than 100 years ago. In addition, petroleum and its derivatives are used in the manufacture of medicines and fertilizers, foodstuffs, plastics, building materials, paints, and cloth and to generate electricity.
CHARACTERISTICS
The chemical composition of all petroleum is principally hydrocarbons, although a few sulfur-containing and oxygen-containing compounds are usually present; the sulfur content varies from about 0.1 to 5 percent. Petroleum contains gaseous, liquid, and solid elements. The consistency of petroleum varies from liquid as thin as gasoline to liquid so thick that it will barely pour. Small quantities of gaseous compounds are usually dissolved in the liquid; when larger quantities of these compounds are present, the petroleum deposit is associated with a deposit of natural gas (see Fuel Gases).
Three broad classes of crude petroleum exist: the paraffin types, the asphaltic types, and the mixed-base types. The paraffin types are composed of molecules in which the number of hydrogen atoms is always two more than twice the number of carbon atoms. The characteristic molecules in the asphaltic types are naphthenes, composed of twice as many hydrogen atoms as carbon atoms. In the mixed-base group are both paraffin hydrocarbons and naphthenes.
See also Asphalt; Naphtha.
FORMATION
Petroleum is formed under Earth’s surface by the decomposition of marine organisms. The remains of tiny organisms that live in the sea—and, to a lesser extent, those of land organisms that are carried down to the sea in rivers and of plants that grow on the ocean bottoms—are enmeshed with the fine sands and silts that settle to the bottom in quiet sea basins. Such deposits, which are rich in organic materials, become the source rocks for the generation of crude oil. The process began many millions of years ago with the development of abundant life, and it continues to this day. The sediments grow thicker and sink into the seafloor under their own weight. As additional deposits pile up, the pressure on the ones below increases several thousand times, and the temperature rises by several hundred degrees. The mud and sand harden into shale and sandstone; carbonate precipitates and skeletal shells harden into limestone; and the remains of the dead organisms are transformed into crude oil and natural gas.
Once the petroleum forms, it flows upward in Earth’s crust because it has a lower density than the brines that saturate the interstices of the shales, sands, and carbonate rocks that constitute the crust of Earth. The crude oil and natural gas rise into the microscopic pores of the coarser sediments lying above. Frequently, the rising material encounters an impermeable shale or dense layer of rock that prevents further migration; the oil has become trapped, and a reservoir of petroleum is formed. A significant amount of the upward-migrating oil, however, does not encounter impermeable rock but instead flows out at the surface of Earth or onto the ocean floor. Surface deposits also include bituminous lakes and escaping natural gas.
CHARACTERISTICS
The chemical composition of all petroleum is principally hydrocarbons, although a few sulfur-containing and oxygen-containing compounds are usually present; the sulfur content varies from about 0.1 to 5 percent. Petroleum contains gaseous, liquid, and solid elements. The consistency of petroleum varies from liquid as thin as gasoline to liquid so thick that it will barely pour. Small quantities of gaseous compounds are usually dissolved in the liquid; when larger quantities of these compounds are present, the petroleum deposit is associated with a deposit of natural gas (see Fuel Gases).
Three broad classes of crude petroleum exist: the paraffin types, the asphaltic types, and the mixed-base types. The paraffin types are composed of molecules in which the number of hydrogen atoms is always two more than twice the number of carbon atoms. The characteristic molecules in the asphaltic types are naphthenes, composed of twice as many hydrogen atoms as carbon atoms. In the mixed-base group are both paraffin hydrocarbons and naphthenes.
See also Asphalt; Naphtha.
FORMATION
Petroleum is formed under Earth’s surface by the decomposition of marine organisms. The remains of tiny organisms that live in the sea—and, to a lesser extent, those of land organisms that are carried down to the sea in rivers and of plants that grow on the ocean bottoms—are enmeshed with the fine sands and silts that settle to the bottom in quiet sea basins. Such deposits, which are rich in organic materials, become the source rocks for the generation of crude oil. The process began many millions of years ago with the development of abundant life, and it continues to this day. The sediments grow thicker and sink into the seafloor under their own weight. As additional deposits pile up, the pressure on the ones below increases several thousand times, and the temperature rises by several hundred degrees. The mud and sand harden into shale and sandstone; carbonate precipitates and skeletal shells harden into limestone; and the remains of the dead organisms are transformed into crude oil and natural gas.
Once the petroleum forms, it flows upward in Earth’s crust because it has a lower density than the brines that saturate the interstices of the shales, sands, and carbonate rocks that constitute the crust of Earth. The crude oil and natural gas rise into the microscopic pores of the coarser sediments lying above. Frequently, the rising material encounters an impermeable shale or dense layer of rock that prevents further migration; the oil has become trapped, and a reservoir of petroleum is formed. A significant amount of the upward-migrating oil, however, does not encounter impermeable rock but instead flows out at the surface of Earth or onto the ocean floor. Surface deposits also include bituminous lakes and escaping natural gas.
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