Water

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Water, common name applied to the liquid state of the hydrogen-oxygen compound H2O. The ancient philosophers regarded water as a basic element typifying all liquid substances. Scientists did not discard that view until the latter half of the 18th century. In 1781 the British chemist Henry Cavendish synthesized water by detonating a mixture of hydrogen and air. However, the results of his experiments were not clearly interpreted until two years later, when the French chemist Antoine Laurent Lavoisier proved that water was not an element but a compound of oxygen and hydrogen. In a scientific paper presented in 1804, the French chemist Joseph Louis Gay-Lussac and the German naturalist Alexander von Humboldt demonstrated jointly that water consisted of two volumes of hydrogen to one of oxygen, as expressed by the present-day formula H2O.

PROPERTIES

Pure water is an odorless, tasteless liquid. It has a bluish tint, which may be detected, however, only in layers of considerable depth. Under standard atmospheric pressure (760 mm of mercury, or 760 torr); the freezing point of water is 0° C (32° F) and its boiling point is 100° C (212° F). Water attains its maximum density at a temperature of 4° C (39° F) and expands upon freezing. Like most other liquids, water can exist in a supercooled state; that is, it may remain a liquid although its temperature is below its freezing point. Water can easily be cooled to about -25° C (-13° F) without freezing, either under laboratory conditions or in the atmosphere itself. Supercooled water will freeze if it is disturbed, if the temperature is lowered further, or if an ice crystal or other particle is added to it. Its physical properties are used as standards to define the calorie and specific and latent heat and in the metric system for the original definition of the unit of mass, the gram.

Water is one of the best-known ionizing agents (see Ionization). Because most substances are somewhat soluble in water, it is frequently called the universal solvent. Water combines with certain salts to form hydrates. It reacts with metal oxides to form acids (see Acids and Bases). It acts as a catalyst in many important chemical reactions.

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