Matter is composed of atoms or groups of atoms called molecules. The arrangement of particles in a material depends on the physical state of the substance. In a solid, particles form a compact structure that resists flow. Particles in a liquid have more energy than those in a solid. They can flow past one another, but they remain close. Particles in a gas have the most energy. They move rapidly and are separated from one another by relatively large distances.

Other Fossil Fuels

Geologists have identified immense deposits of other hydrocarbons, including gas hydrates (methane and water), tar sands, and oil shale. Vast deposits of gas hydrates are contained in ocean sediments and in shallow polar soils. In these marine and polar environments, methane molecules are encased in a crystalline structure with water molecules. This crystalline solid is known as gas hydrate. Because technology for the commercial extraction of gas hydrates has not yet been developed, this type of fossil fuel is not included in most world energy resource estimates.

Tar sands are heavy, asphaltlike hydrocarbons found in sandstone. Tar sands form where petroleum migrates upward into deposits of sand or consolidated sandstone. When the petroleum is exposed to water and bacteria present in the sandstone, the hydrocarbons often degrade over time into heavier, asphaltlike bitumen. Oil shale is a fine-grained rock containing high concentrations of a waxy organic material known as kerogen. Oil shale forms on lake and ocean bottoms where dead algae, spores, and other microorganisms died millions of years ago and accumulated in mud and silt. The increasing pressure and temperature from the buildup of overlying sediments transformed the organic material into kerogen and compacted the mud and silt into oil shale. However, this pressure and heat was insufficient to chemically break down the kerogen into petroleum. Because the hydrocarbons contained in tar sand and oil shale are not fluids, these hydrocarbons are more difficult and costly to recover than liquid petroleum.

Removing and Refining Fossil Fuels

Geologists use a variety of sophisticated instruments to locate underground petroleum, natural gas, and coal deposits. These instruments allow scientists to interpret the geologic composition, history, and structure of sedimentary basins in the earth’s crust. Once located, petroleum and natural gas deposits are removed by wells drilled down into the deposit, while coal is removed by excavation.

Petroleum and Natural Gas
To locate deposits of petroleum and natural gas, exploration geologists search for geologic regions containing the ingredients necessary for petroleum formation: organic-rich source rock, burial temperatures sufficiently high to generate petroleum from organic material, and petroleum-trapping rock formations.

When potentially petroleum-rich geologic formations are identified, wells are drilled into the sedimentary basin. If a well intersects porous reservoir rock containing significant petroleum and natural gas deposits, pressure inside the trap may force the liquid hydrocarbons spontaneously to the surface. However, pressure inside the trap typically declines to the point where the petroleum must be pumped to the surface.

Once petroleum has been extracted from the ground, it is transported by pipeline, truck, or tanker to a refinery to be separated into liquid and gas components. Raw petroleum is heated to distill hydrocarbons by molecular weight. Lighter molecules are separated and refined into gasoline and other fuels, while heavier molecules are processed into engine lubricants, asphalt, waxes, and other products. Because demand for fuel far exceeds demand for the products made from the heavier hydrocarbons, refiners often break apart the heavy molecules into lighter ones that can be refined into gasoline. They do so by means of processes called thermal cracking and catalytic cracking.

Coal
Because of their enormity, the world’s most extensive coal beds have already been identified. Modern underground mining commonly employs machines called longwall miners to remove coal. These machines use rotating drums studded with picks to rip coal from seams in large chunks.

Surface-mine operators use mammoth earth-moving shovels to mine coal. These shovels first remove overlying soil and rock so the coal beds can be blasted apart. The blasted coal is scooped up and loaded into the beds of huge trucks for transport.

Fossil Fuels: Commercial Uses

Once fossil fuel has been extracted and processed, it can be burned for direct uses, such as to power cars or heat homes, or it can be combusted for the generation of electrical power.

Direct Combustion
Fossil fuels are primarily burned to produce energy. This energy is used to power automobiles, trucks, airplanes, trains, and ships around the world; to fuel industrial manufacturing processes; and to provide heat, light, air conditioning, and energy for homes and businesses.

To provide fuel for transportation, petroleum is refined into gasoline, diesel fuel, jet fuel, and other derivatives used in most of the world’s automobiles, trucks, trains, aircraft, and ships.

Demand for natural gas, historically considered a waste by-product of petroleum and coal mining, is growing in business and industry because it is a cleaner-burning fuel than petroleum or coal. Natural gas, which can be piped directly to commercial plants or individual residences and used on demand, is used for heating and for air conditioning. Residential uses of natural gas also include fuel for stoves and other heating appliances.

Electricity Generation
In addition to direct combustion for commercial uses, fossil fuels are also burned to generate most of the world’s electric power. In 2001 fossil fuel fired power plants produced 64 percent of the world’s electrical power, down from 71 percent in the late 1970s. In 2001 the world’s remaining electricity supply was generated primarily by hydroelectric power (17 percent) and nuclear fission (17 percent), with solar, geothermal, and other sources accounting for a relatively small amount.

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