Compound

Compound, in chemistry, a substance composed of atoms of two or more elements in chemical combination, occurring in a fixed, definite proportion and arranged in a fixed, definite structure. A compound is often represented by its chemical formula. The formula for water is H₂O, and for sodium chloride, NaCl. The formula weight of a compound can be determined from its formula. The molecular weight of a molecular compound can be determined from its molecular formula. Two or more distinct compounds that have the same molecular formula but different properties are called isomers.

Formation and Decomposition of Compounds

Compounds are formed from simpler substances by chemical reaction. Some compounds can be formed directly from their constituent elements, e.g., water from hydrogen and oxygen: 2H₂ + O₂ → 2H₂O. Other compounds are formed by reaction of an element with another compound; e.g., sodium hydroxide (NaOH) is formed (and hydrogen gas released) by the reaction of sodium metal with water: 2Na + 2H₂O → 2NaOH + H₂↑. Compounds are also made by reaction of other compounds; e.g., sodium hydroxide reacts with hydrogen chloride (HCl) to form sodium chloride and water: HCl + NaOH → NaCl + H₂O. Complex molecules such as proteins are formed by a series of reactions involving elements and simple compounds.

Compounds can be decomposed by chemical means into elements or simpler compounds. Water is broken down into hydrogen and oxygen by electrolysis. Candle wax, a mixture of hydrocarbons, is changed in the candle flame by combustion (with oxygen) to a mixture of the simpler compounds carbon dioxide (CO₂) and water. Life is based on numerous reactions in which energy is stored and released as compounds are produced and decomposed.

Properties of Compounds

A compound has unique properties that are distinct from the properties of its elemental constituents. One familiar chemical compound is water, a liquid that is nonflammable and does not support combustion. It is composed of two elements: hydrogen, an extremely flammable gas, and oxygen, a gas that supports combustion. A compound differs from a mixture in that the components of a mixture retain their own properties and may be present in many different proportions. The components of a mixture are not chemically combined; they can be separated by physical means. A mixture of hydrogen and oxygen gases is still a gas and can be separated by physical methods. If the mixture is ignited, however, the two gases undergo a rapid chemical combination to form water. Although the hydrogen and oxygen can occur in any proportion in a mixture of gases, they are always combined in the exact proportion of two atoms of hydrogen to one atom of oxygen when combined in the compound water. Another familiar compound is sodium chloride (common salt). It is composed of the silvery metal sodium and the greenish poisonous gas chlorine combined in the proportion of one atom of sodium to one atom of chlorine.

Molecular and Ionic Compounds

Water is a molecular compound; it is made up of electrically neutral molecules, each containing a fixed number of atoms. Sodium chloride is an ionic compound; it is made up of electrically charged ions that are present in fixed proportions and are arranged in a regular, geometric pattern (called crystalline structure) but are not grouped into molecules. The atoms in a compound are held together by chemical bonding.

Synthetic Elements / Transactinide Elements

Synthetic elements, in chemistry, radioactive elements that were not discovered occurring in nature but as artificially produced isotopes. They are technetium (at. no. 43), which was the first element to be synthesized, promethium (at. no. 61), astatine (at. no. 85), francium (at. no. 87), and the transuranium elements (at. no. 93 and beyond in the periodic table). Some of these elements have since been shown to exist in minute amounts in nature, usually as short-lived members of natural radioactive decay series (see radioactivity).

The synthetic elements through at. no. 100 (fermium) are created by bombarding a heavy element, such as uranium or plutonium, with neutrons or alpha particles. The synthesis of the transfermium elements (elements with at. no. 101 or greater) is accomplished by the fusion of the nuclei of two lighter elements. Elements 101 through 106 were first produced by fusing the nuclei of slightly lighter elements, such as californium, with those of light elements, such as carbon. Elements 107 through 112 were first produced by fusing the nuclei of medium-weight elements, such as bismuth or lead, with those of other medium-weight elements, such as iron, nickel, or zinc. Element 114 was first produced by fusing the nuclei of plutonium and calcium and subsequently by fusing the nuclei of lead and krypton, as was element 116. Element 115 was produced by bombarding americium with calcium, and element 113 resulted from the radioactive decay of element 115. The claim by Lawrence Berkeley National Laboratory to have created element 118 has been retracted.)

The transfermium elements are produced in very small quantities (one atom at a time), and identification is therefore very difficult because of half-lives ranging from minutes to milliseconds and the need to identify the products by methods other than known chemical separations. This has led to controversy over reported discoveries and over the naming of the elements. It has been predicted that one isotope of element 114—containing 114 protons and 184 neutrons—would be very stable because its nucleus would have a full complement of protons and neutrons. Termed an "island of stability," its half-life might be measured in years. However, none of the three isotopes of element 114 synthesized as yet have as many as 184 neutrons, and their half-lives are still in the millisecond range.

Transactinide elements (chemistry), in the periodic table, elements with atomic numbers higher than 103.

Ununhexium

Ununhexium, artificially produced radioactive chemical element; symbol Uuh; at. no. 116; mass number of most stable isotope 292; m.p., b.p., sp. gr., and valence unknown. Situated in Group 16 of the periodic table, it is expected to have properties similar to those of polonium and tellurium.

In 1999 a research team at the Lawrence Berkeley National Laboratory in Calif. bombarded lead-208 atoms with high-energy krypton-86 ions to create, apparently, ununoctium (element 118) atoms. The Uuo-293 isotope that they synthesized emitted an alpha particle to decay into Uuh-289, which has a life-life of about 0.6 millisecond, which then emitted an alpha particle to decay into ununquadium (element 114). Although the Berkeley laboratory retracted its claim for creating ununoctium in 2001, other research teams have since created ununhexium directly. No name has yet been adopted for element 116, which is therefore called ununhexium, from the Latin roots un for one and hex for six, under a convention for neutral temporary names proposed by the International Union of Pure and Applied Chemistry (IUPAC) in 1980.